Safety data sheet for Glycerin

CAS 56-81-5

This is the free preview of a draft SDS for Glycerin — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Soap, lotion, cosmetics, food.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
56-81-5
Molecular formula
C3H8O3
Molecular weight
92.09 g/mol
Signal word
None required — not classified

Hazard classification

  • Not Classified

Section 1 — Identification

1.1 Product identifier

Product identifier: Glycerol

Chemical name (IUPAC): propane-1,2,3-triol

CAS number: 56-81-5

PubChem CID reference: 753

Synonyms: glycerol; glycerin; Glycerine; 1,2,3-Propanetriol; Glycyl alcohol; Trihydroxypropane; Glyceritol; Osmoglyn; 1,2,3-trihydroxypropane; Glyrol

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Laboratory reagent, industrial processing aid, formulation component, and internal product-stewardship review subject to supplier confirmation.

Uses advised against: Consumer, medical, food, or any other use not covered by the supplier's label, technical instructions, or exposure scenario.

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification: Not classified as hazardous according to the sources named below.

2.2 Label elements

Signal word: Not available

GHS pictograms: None

Hazard statement: Not classified

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Liquid

Appearance: Syrupy, rhombic plates

Odor: MILD ODOR

Boiling point: 263°C (505°F) at 1013 hPa

Melting point: 18.1°C (65°F)

Flash point: 176°C (349°F) closed cup

Density: 1.2613 g/cm³ at 20°C

Vapor pressure: 5.3 hPa at 25°C

Water solubility: Miscible

Log Pow (log Kow): -1.76

Vapor density: 3.17 (air = 1)

Lower explosive limit: Not available

Upper explosive limit: Not available

Auto-ignition temperature: 393°C (739°F)

Viscosity: 954 CENTIPOISES AT 25 °C; 17 CENTIPOISES AT 25 °C (70% SOLN)

pH: Not available

9.2 Other information

Other information: Additional classification-supporting physical hazard data should be confirmed from the customer-specific product specification where required.

Sources

  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Glycerin, and where each one comes from

33 measured values for 12 properties, read from 4 public databases. On 4 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

4 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

554 °F (Decomposes)
NIOSH Pocket Guide

Melting point

4 records agree

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Flash point

3 records, 160 to 177 °C

The lowest temperature at which the liquid gives off enough vapour to ignite. It decides the GHS flammable liquid category.

Auto-ignition temperature

1 record

The temperature at which the substance ignites with no spark or flame. It sets safe surface and process temperatures.

Explosive limits

1 record

The vapour concentration range in air that will burn. Below the lower limit and above the upper limit it will not.

Confined mixture with chlorine explodes if heated to 70 - 80 degree
Hazardous Substances Data Bank (HSDB)

Vapour pressure

4 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

VP: 0.0025 MM HG AT 50 °C
Hazardous Substances Data Bank (HSDB)
1.68X10-4 mm Hg at 25 °C
Hazardous Substances Data Bank (HSDB)
(122 °F): 0.003 mmHg
NIOSH Pocket Guide

Vapour density

2 records differ

Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.

Density

5 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

A trihydric (polyhydric) alcohol; hygroscopic; density (anhydrous): 1.2653; density (USP): >1.249 at 25 °C/25 °C; density (dynamite): 1.2620
Hazardous Substances Data Bank (HSDB)

Solubility

5 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

Miscible with ethanol; slightly soluble in ethyl ether; insoluble in benzene, carbon tetrachloride, chloroform, carbon disulfide, petroleum ether
Hazardous Substances Data Bank (HSDB)
SOLUBILITY IN ACETONE: 1 G IN 15 ML
Hazardous Substances Data Bank (HSDB)
Insoluble in fixed and volatile oils
Hazardous Substances Data Bank (HSDB)
In water, 5.296X10+6 mg/L at 25 °C
Hazardous Substances Data Bank (HSDB)

Partition coefficient (log Kow)

1 record

Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.

Viscosity

1 record

Governs how far a spill spreads and how fast it soaks into a surface or a sorbent.

954 CENTIPOISES AT 25 °C; 17 CENTIPOISES AT 25 °C (70% SOLN)
Hazardous Substances Data Bank (HSDB)

Odour

2 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

These are the public records read for Glycerin, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Glycerin

The draft covers all 16 sections under OSHA 29 CFR 1910.1200 and GHS Rev. 7, or the CLP EC 1272/2008 layout for the EU. Each draft arrives as an editable .docx and a PDF with an appendix naming the source of each value, in about 60 seconds. $5 per document, no account.

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