Safety data sheet for Ethyl acetate

CAS 141-78-6

This is the free preview of a draft SDS for Ethyl acetate — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Nail products, coatings, flavour and fragrance.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
141-78-6
Molecular formula
C4H8O2
Molecular weight
88.11 g/mol
Signal word
Danger

Hazard classification

  • GHS02 — Flammable
  • GHS07 — Health hazard — irritant
  • H225: Highly Flammable liquid and vapor.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.

Section 1 — Identification

1.1 Product identifier

Product identifier: Ethyl Acetate

Chemical name (IUPAC): ethyl acetate

CAS number: 141-78-6

PubChem CID reference: 8857

Synonyms: ETHYL ACETATE; Ethyl ethanoate; Acetic acid ethyl ester; Vinegar naphtha; Acetoxyethane; Acetic ether; Ethyl acetic ester; Acetic acid, ethyl ester; Acetidin; Ethylacetate

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Laboratory reagent, industrial processing aid, formulation component, and internal product-stewardship review subject to supplier confirmation.

Uses advised against: Consumer, medical, food, or any other use not covered by the supplier's label, technical instructions, or exposure scenario.

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes.

Classification: Flammable Liquid, Category 2 (Flam. Liq. 2) [H225]

Classification: Eye Irritation, Category 2 (Eye Irrit. 2) [H319]

Classification: Specific Target Organ Toxicity, Single Exposure, Category 3 (STOT SE 3) [H336]

2.2 Label elements

Signal word: Danger

GHS pictograms: GHS02 (Flammable), GHS07 (Exclamation)

Hazard statement: H225: Highly Flammable liquid and vapor.

Hazard statement: H319: Causes serious eye irritation.

Hazard statement: H336: May cause drowsiness or dizziness.

Precautionary statement: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Precautionary statement: P264+P265: Wash hands thoroughly after handling. Do not touch eyes.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

Precautionary statement: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Precautionary statement: P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Liquid

Appearance: Clear, colorless liquid

Odor: Sweet, fruity

Boiling point: 75-78°C

Melting point: -83.5°C

Flash point: -4°C closed cup

Density: 0.902 g/cm³ at 20°C

Vapor pressure: 103 mbar at 20°C

Water solubility: 80 g/L at 25°C (Source: PubChem / HSDB; Fisher supplier SDS standard)

Log Pow (log Kow): 0.73

Vapor density: 3.04 (air = 1)

Lower explosive limit: 2%

Upper explosive limit: 12%

Auto-ignition temperature: 427°C

Viscosity: 0.45 cP at 20°C

pH: Not applicable

9.2 Other information

Other information: Additional classification-supporting physical hazard data should be confirmed from the customer-specific product specification where required.

Sources

  • ECHA C&L Inventory — harmonised CLP entry
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Ethyl acetate, and where each one comes from

34 measured values for 11 properties, read from 4 public databases. On 4 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

4 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

4 records, -84 to 47 °C

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Flash point

2 records agree

The lowest temperature at which the liquid gives off enough vapour to ignite. It decides the GHS flammable liquid category.

Explosive limits

1 record

The vapour concentration range in air that will burn. Below the lower limit and above the upper limit it will not.

Explosive limits mol fraction in air: Upper 0.090, Lower 0.025
Hazardous Substances Data Bank (HSDB)

Vapour pressure

4 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

75 [mm Hg] @20.399999999999999 °C
PAC Chemical Database, U.S. Department of Energy

Vapour density

2 records differ

Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.

Density

5 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

DENSITY OF SATURATED AIR (AIR= 1) 1.02; CONVERSION FACTORS: 1 MG/L= 278 PPM; 1 PPM= 3.60 MG/CU M
Hazardous Substances Data Bank (HSDB)

Solubility

6 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

In water, 8.0X10+4 mg/L at 25 °C
Hazardous Substances Data Bank (HSDB)
Very soluble in water (64 g/L at 25 °C)
Hazardous Substances Data Bank (HSDB)
Miscible with ethanol, ethyl ether; very soluble in acetone, benzene
Hazardous Substances Data Bank (HSDB)
For more Solubility (Complete) data for ETHYL ACETATE (6 total), please visit the HSDB record page
Hazardous Substances Data Bank (HSDB)
(77 °F): 10%
NIOSH Pocket Guide

Partition coefficient (log Kow)

1 record

Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.

Viscosity

1 record

Governs how far a spill spreads and how fast it soaks into a surface or a sorbent.

Odour

4 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

CHARACTERISTIC ETHER-LIKE ODOR REMINISCENT OF PINEAPPLE
Hazardous Substances Data Bank (HSDB)
Fruity with a brandy note
Hazardous Substances Data Bank (HSDB)

These are the public records read for Ethyl acetate, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Ethyl acetate

The draft covers all 16 sections under OSHA 29 CFR 1910.1200 and GHS Rev. 7, or the CLP EC 1272/2008 layout for the EU. Each draft arrives as an editable .docx and a PDF with an appendix naming the source of each value, in about 60 seconds. $5 per document, no account.

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