Safety data sheet for D-Limonene
CAS 5989-27-5
This is the free preview of a draft SDS for D-Limonene — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.
Typically documented by: Citrus degreasers, natural cleaning products.
Draft safety data sheet — preview
Sections 1, 2, 9 of 16
- CAS number
- 5989-27-5
- Molecular formula
- C10H16
- Molecular weight
- 136.23 g/mol
- Signal word
- Danger
Hazard classification
- GHS02 — Flammable
- GHS07 — Health hazard — irritant
- GHS08 — Serious health hazard
- GHS09 — Hazardous to the environment
- H226: Flammable liquid and vapor.
- H304: May be fatal if swallowed and enters airways.
- H315: Causes skin irritation.
- H317: May cause an allergic skin reaction.
- H400: Very toxic to aquatic life.
- H410: Very toxic to aquatic life with long lasting effects.
- H412: Harmful to aquatic life with long lasting effects.
Section 1 — Identification
1.1 Product identifier
Product identifier: D-Limonene
Chemical name (IUPAC): (4R)-1-methyl-4-prop-1-en-2-ylcyclohexene
CAS number: 5989-27-5
PubChem CID reference: 440917
Synonyms: D-Limonene; (+)-Limonene; (R)-(+)-Limonene; (D)-Limonene; (+)-(4R)-Limonene; (4R)-Limonene; (R)-4-Isopropenyl-1-methyl-1-cyclohexene; D-(+)-Limonene; (+)-Dipentene; Limonene, (+)-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory reagent, industrial processing aid, formulation component, and internal product-stewardship review subject to supplier confirmation.
Uses advised against: Consumer, medical, food, or any other use not covered by the supplier's label, technical instructions, or exposure scenario.
Section 2 — Hazards Identification
2.1 Classification of the substance or mixture
Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes.
Classification: Flammable Liquid, Category 3 (Flam. Liq. 3) [H226]
Classification: Aspiration Hazard, Category 1 (Asp. Tox. 1) [H304]
Classification: Skin Irritation, Category 2 (Skin Irrit. 2) [H315]
Classification: Hazardous to the Aquatic Environment, Long-Term Hazard, Category 3 (Aquatic Chronic 3) [H412]
2.2 Label elements
Signal word: Danger
GHS pictograms: GHS02 (Flammable), GHS07 (Exclamation), GHS08 (Health Hazard), GHS09 (Environmental Hazard)
Hazard statement: H226: Flammable liquid and vapor.
Hazard statement: H304: May be fatal if swallowed and enters airways.
Hazard statement: H315: Causes skin irritation.
Hazard statement: H317: May cause an allergic skin reaction.
Hazard statement: H400: Very toxic to aquatic life.
Hazard statement: H410: Very toxic to aquatic life with long lasting effects.
Hazard statement: H412: Harmful to aquatic life with long lasting effects.
Precautionary statement: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.
Precautionary statement: P233: Keep container tightly closed.
Precautionary statement: P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
Precautionary statement: P301+P316: IF SWALLOWED: Get emergency medical help immediately.
Precautionary statement: P302+P352: IF ON SKIN: Wash with plenty of water.
Section 9 — Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Physical form: Liquid
Appearance: Oil
Odor: Citrus odor
Boiling point: 177.6°C (352°F) at 1013 hPa
Melting point: -74°C (-101°F)
Flash point: 48°C (118°F) closed cup
Density: 0.8411 at 20 °C
Vapor pressure: 2.6 hPa at 25°C
Water solubility: Miscible
Log Pow (log Kow): 4.57
Vapor density: 4.69 (air = 1)
Lower explosive limit: Not available
Upper explosive limit: Not available
Auto-ignition temperature: 237°C (459°F)
Viscosity: Not available
pH: Not available
9.2 Other information
Other information: Additional classification-supporting physical hazard data should be confirmed from the customer-specific product specification where required.
Sources
- PubChem — GHS classification
- PubChem — compound record
- PubChem — names and identifiers
- PubChem — regulatory information
- PubChem — toxicity data
- PubChem — transport information
Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.
Measured values for D-Limonene, and where each one comes from
17 measured values for 11 properties, read from 2 public databases. On 2 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.
Boiling point
2 records agree
Used with vapour pressure to judge how readily the substance reaches the air you breathe.
- 178 °C @760 [mm Hg]
- PAC Chemical Database, U.S. Department of Energy
Melting point
2 records agree
Fixes the physical state at handling temperature, which the label and the transport class depend on.
Flash point
1 record
The lowest temperature at which the liquid gives off enough vapour to ignite. It decides the GHS flammable liquid category.
- 48 °C (closed cup)
- Hazardous Substances Data Bank (HSDB)
Auto-ignition temperature
1 record
The temperature at which the substance ignites with no spark or flame. It sets safe surface and process temperatures.
Explosive limits
1 record
The vapour concentration range in air that will burn. Below the lower limit and above the upper limit it will not.
- Upper explosion limit: 6,1 %(V); Lower explosion limit: 0,7 %(V)
- Hazardous Substances Data Bank (HSDB)
Vapour pressure
2 records differ
The higher it is, the faster the substance evaporates into the workplace air at room temperature.
- 1.98 mm Hg at 25 °C
- Hazardous Substances Data Bank (HSDB)
- 1.98 [mm Hg] @25 °C
- PAC Chemical Database, U.S. Department of Energy
Vapour density
1 record
Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.
- 4.7 (Air = 1)
- Hazardous Substances Data Bank (HSDB)
Density
2 records differ
Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.
- 0.8411 at 20 °C
- Hazardous Substances Data Bank (HSDB)
Solubility
3 records, each a different case
Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.
- In water, 13.8 mg/L at 25 °C
- Hazardous Substances Data Bank (HSDB)
- Miscible with ethanol and ether; soluble in carbon tetrachloride
- Hazardous Substances Data Bank (HSDB)
- Miscible with fixed oils; slightly soluble in glycerin; insoluble in propylene glycol
- Hazardous Substances Data Bank (HSDB)
Partition coefficient (log Kow)
1 record
Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.
- log Kow = 4.57
- Hazardous Substances Data Bank (HSDB)
Odour
1 record
Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.
- Citrus odor
- Hazardous Substances Data Bank (HSDB)
These are the public records read for D-Limonene, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.
Get the full draft SDS for D-Limonene
The draft covers all 16 sections under OSHA 29 CFR 1910.1200 and GHS Rev. 7, or the CLP EC 1272/2008 layout for the EU. Each draft arrives as an editable .docx and a PDF with an appendix naming the source of each value, in about 60 seconds. $5 per document, no account.