Safety data sheet for Amorphous silica

CAS 7631-86-9

This is the free preview of a draft SDS for Amorphous silica — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Anti-caking agent, desiccant, coatings.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
7631-86-9
Molecular formula
SiO2
Molecular weight
60.084 g/mol
Signal word
Warning

Hazard classification

  • GHS07 — Health hazard — irritant
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.

Section 1 — Identification

1.1 Product identifier

Product identifier: Silica

Chemical name (IUPAC): dioxosilane

CAS number: 7631-86-9

EC number: 231-545-4

REACH registration number: Not required for substances manufactured/imported <1 tonne/year; otherwise confirm the active registrant number before external issue.

IUPAC name: dioxosilane

PubChem CID reference: 24261

Synonyms: SILICON DIOXIDE; Silica; Dioxosilane; Silicic anhydride; Diatomaceous silica; Wessalon; Zorbax sil; Silica, amorphous; Silica, colloidal; Sillikolloid

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Laboratory reagent, industrial processing aid, formulation component, and internal product-stewardship review subject to supplier confirmation.

Uses advised against: Consumer, medical, food, or any other use not covered by the supplier's label, technical instructions, or exposure scenario.

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification: Skin Irritation, Category 2 (Skin Irrit. 2) [H315]

Classification: Eye Irritation, Category 2 (Eye Irrit. 2) [H319]

Classification: Specific Target Organ Toxicity, Single Exposure, Category 3 (STOT SE 3) [H335]

2.2 Label elements

Signal word: Warning

GHS pictograms: GHS07 (Exclamation)

Hazard statement: H315: Causes skin irritation.

Hazard statement: H319: Causes serious eye irritation.

Hazard statement: H335: May cause respiratory irritation.

Precautionary statement: P264+P265: Wash hands thoroughly after handling. Do not touch eyes.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P271: Use only outdoors or in a well-ventilated area.

Precautionary statement: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Precautionary statement: P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Precautionary statement: P302+P352: IF ON SKIN: Wash with plenty of water.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Solid

Appearance: Amorphous powder

Odor: Odorless

Boiling point: 2230°C (4046°F) at 1013 hPa

Melting point: 1710°C (3110°F)

Flash point: Not available

Density: 2.2 @ 25 °C

Vapor pressure: 0 hPa

Water solubility: none

Log Pow (log Kow): Not available

Vapor density: Not available

Lower explosive limit: Not available

Upper explosive limit: Not available

Auto-ignition temperature: Not available

Viscosity: Not available

pH: Not available

9.2 Other information

Other information: Additional classification-supporting physical hazard data should be confirmed from the customer-specific product specification where required.

Sources

  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Amorphous silica, and where each one comes from

26 measured values for 6 properties, read from 3 public databases. On 4 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

3 records, 2230 to 2950 °C

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

3 records, 1710 to 1722 °C

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Vapour pressure

3 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

0 mmHg (approx)
NIOSH Pocket Guide

Density

11 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

Colorless crystals or white powder; odorless and tasteless; density: 2.2-2.6; soluble in molten alkai when finely divided and amorphous /Silicon dioxide/
Hazardous Substances Data Bank (HSDB)
Density = 2.648 /alpha-Quartz/ /from table/
Hazardous Substances Data Bank (HSDB)
Density = 2.269 /alpha-Tridymite/ /from table/
Hazardous Substances Data Bank (HSDB)
Density = 2.318 /alpha-Cristobalite/ /from table/
Hazardous Substances Data Bank (HSDB)
Density = 2.909 /Coesite/ /from table/
Hazardous Substances Data Bank (HSDB)
Density = 4.287 /Stishovite/ /from table/
Hazardous Substances Data Bank (HSDB)

Solubility

5 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

AMORPHOUS IS SOL IN ALKALIES, ESP WHEN FINELY DIVIDED
Hazardous Substances Data Bank (HSDB)
Very slightly sol in alkali
Hazardous Substances Data Bank (HSDB)
The external amorphous layer in quartz (the Beilby layer) is more soluble than the crystalline underlying core
Hazardous Substances Data Bank (HSDB)

Odour

1 record

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

These are the public records read for Amorphous silica, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Amorphous silica

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